Issue 43, 2009
From the journal:

Chemical Communications

A tetranuclear iridium(iii) complex with a flavin analogue as a bridging ligand in different coordination modes and exchangeable anion encapsulation in a supramolecular cage†

Takahiko Kojima,*a   Yuji Inui,b   Soushi Miyazaki,b   Motoo Shiroc  and  Shunichi Fukuzumi*b  

* Corresponding authors

a Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennoudai, Tsukuba, Ibaraki 305-8571, Japan
E-mail: kojima@chem.tsukuba.ac.jp
Fax: (+81) 29-853-4323

b Department of Material and Life Science, Graduate School of Engineering, Osaka University and SORST (JST), 2-1 Yamada-oka, Suita, Osaka 565-0871, Japan
E-mail: fukuzumi@chem.eng.osaka-u.ac.jp
Fax: (+81) 6-6879-7370

c X-ray Laboratory, Rigaku Corporation, 3-9-12 Matsubara, Akishima, Tokyo 196-8666, Japan

Abstract

A novel tetranuclear Ir(III) complex involving unprecedented coordination modes of alloxazine formed a closed π-space by intermolecular hydrogen bonding and the counter anions encapsulated in the space could be exchanged viaself-assembly.

Graphical abstract: A tetranuclear iridium(iii) complex with a flavin analogue as a bridging ligand in different coordination modes and exchangeable anion encapsulation in a supramolecular cage

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Article information

DOI
https://doi.org/10.1039/B911033J
Article type
Communication
Submitted
04 Jun 2009
Accepted
09 Sep 2009
First published
25 Sep 2009

Chem. Commun., 2009, 6643-6645

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A tetranuclear iridium(III) complex with a flavin analogue as a bridging ligand in different coordination modes and exchangeable anion encapsulation in a supramolecular cage

T. Kojima, Y. Inui, S. Miyazaki, M. Shiro and S. Fukuzumi, Chem. Commun., 2009, 6643 DOI: 10.1039/B911033J

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