The preparation of the MF6− (M = As, Sb) salts of 1,4-benzoquinodal bridged bis-1,3,2-dithiazolylium utilizing the cycloaddition and oxidative dehydrogenation chemistry of SNSMF6 and observation of a hybrid semiquinoidal–thiazyl radical-cation by EPR

Andreas Decken; Aaron Mailman; Jack Passmore

doi:10.1039/B910338D

skip RSC | ChemSpider | Feedback

Home > Journals > Chemical Communications > The preparation of the ...

Authors & Referees | Librarians

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Chemical Communications

Issue 40, 2009

More about this Journal
Editorial Board
Submit an Article

Follow Journal | |

Journal Home | RSC Journals

Communication

Previous Article | Next Article

The preparation of the MF₆⁻ (M = As, Sb) salts of 1,4-benzoquinodal bridged bis-1,3,2-dithiazolylium utilizing the cycloaddition and oxidative dehydrogenation chemistry of SNSMF₆ and observation of a hybrid semiquinoidal–thiazyl radical-cation by EPR

Andreas Decken , Aaron Mailman and Jack Passmore

Chem. Commun., 2009, 6077-6079

DOI: 10.1039/B910338D
Received 27 May 2009, Accepted 06 Aug 2009
First published on the web 25 Aug 2009

Please wait while Download options loads

Request Permissions

Abstract
Cited by
Compounds
Related Content

SNSMF₆ (M = As, Sb) reacts with 1,4-benzoquinone in a series of cycloaddition and oxidative dehydrogenation reactions to give 3 (MF₆)₂ which on reduction with CsI yields the unique semiquinodal–thiazyl radical-cation (3⁺˙) as observed by X-band solution ESR and supported by DFT calculations.