Issue 32, 2009
From the journal:

Chemical Communications

Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines†‡

Kazuhiro Okamoto,a   Tamio Hayashi*a  and  Viresh H. Rawalb  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto, Japan
E-mail: thayashi@kuchem.kyoto-u.ac.jp
Fax: +81 75 753 3988
Tel: +81 75 753 3983

b Department of Chemistry, the University of Chicago, 5735 South Ellis Avenue, Chicago, Illinois, USA

Abstract

Rhodium-catalyzed asymmetric arylation of imines using electronically and sterically-modified chiral diene ligands gave the corresponding diarylmethylamines in high yield and with high enantioselectivity using just 0.3 mol% of catalyst.

Graphical abstract: Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines

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Article information

DOI
https://doi.org/10.1039/B904624K
Article type
Communication
Submitted
06 Mar 2009
Accepted
24 Apr 2009
First published
19 May 2009

Chem. Commun., 2009, 4815-4817

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Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines

K. Okamoto, T. Hayashi and V. H. Rawal, Chem. Commun., 2009, 4815 DOI: 10.1039/B904624K

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