Issue 14, 2009
From the journal:

Chemical Communications

Palladium-catalyzed cross-couplings of 1,3-butadien-2-yl species with organoindiums generated from allenylmethyl bromide and indium†‡

Sundae Kim,a   Dong Seomoona  and  Phil Ho Lee*a  

* Corresponding authors

a Department of Chemistry and Institute for Molecular Science and Fusion Technology, Kangwon National University, Republic of Korea
E-mail: phlee@kangwon.ac.kr
Fax: +83 33 253 7582
Tel: +82 33 250 8493

Abstract

An organoindium generated from the reaction of indium with allenylmethyl bromide is an efficient nucleophile in Pd-catalyzed cross-couplings, producing 1,3-butadienes; cross-couplings followed by [4 + 2] cycloadditions gave six-membered carbocycles in a one-pot process.

Graphical abstract: Palladium-catalyzed cross-couplings of 1,3-butadien-2-yl species with organoindiums generated from allenylmethyl bromide and indium

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Article information

DOI
https://doi.org/10.1039/B823037D
Article type
Communication
Submitted
22 Dec 2008
Accepted
23 Jan 2009
First published
23 Feb 2009

Chem. Commun., 2009, 1873-1875

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Palladium-catalyzed cross-couplings of 1,3-butadien-2-yl species with organoindiums generated from allenylmethyl bromide and indium

S. Kim, D. Seomoon and P. H. Lee, Chem. Commun., 2009, 1873 DOI: 10.1039/B823037D

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