Issue 17, 2009
From the journal:

Chemical Communications

Neutral and ionic reaction mechanisms for the allylation of aldehydes by bipyridineN,N′-dioxides†

Radim Hrdina,a   František Opekar,b   Jana Roithová*ac  and  Martin Kotora*ac  

* Corresponding authors

a Dept. of Organic and Nuclear Chemistry, Faculty of Science, Charles University, Hlavova 8, Czech Republic
E-mail: kotora@natur.cuni.cz, roithova@natur.cuni.cz
Fax: +420 221 951 326
Tel: +420 221 951 334

b Dept. of Analytical Chemistry, Faculty of Science, Charles University, Hlavova 8, Czech Republic
E-mail: opekar@natur.cuni.cz

c Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo n. 2, Czech Republic

Abstract

Experimental as well as theoretical calculations provide evidence that the allylation of aldehydes catalyzed by bipyridineN,N′-dioxides proceeds via two different reaction mechanisms depending on the solvent used.

Graphical abstract: Neutral and ionic reaction mechanisms for the allylation of aldehydes by bipyridineN,N′-dioxides

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Article information

DOI
https://doi.org/10.1039/B819545E
Article type
Communication
Submitted
03 Nov 2008
Accepted
20 Feb 2009
First published
11 Mar 2009

Chem. Commun., 2009, 2314-2316

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Neutral and ionic reaction mechanisms for the allylation of aldehydes by bipyridineN,N′-dioxides

R. Hrdina, F. Opekar, J. Roithová and M. Kotora, Chem. Commun., 2009, 2314 DOI: 10.1039/B819545E

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