New structural types and different oxidation levels in the family of Mn6-oxime single-molecule magnets

Leigh F. Jones; Ross Inglis; Martyn E. Cochrane; Kevin Mason; Anna Collins; Simon Parsons; Spyros P. Perlepes; Euan K. Brechin

doi:10.1039/B811143J

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Dalton Transactions

Issue 44, 2008

The international journal for inorganic, organometallic and bioinorganic chemistry

Impact Factor 3.838 48 Issues per Year Indexed in MEDLINE

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New structural types and different oxidation levels in the family of Mn₆-oxime single-molecule magnets

Leigh F. Jones,^a Ross Inglis,^a Martyn E. Cochrane,^a Kevin Mason,^a Anna Collins,^a Simon Parsons,^a Spyros P. Perlepes^b and Euan K. Brechin*^a

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School of Chemistry, Joseph Black Building, West Mains Road, Edinburgh, UK
E-mail: ebrechin@staffmail.ed.ac.uk ;
Tel: +44 (0)131 650 7545

School of Chemistry, University of Patras, 26504 Patras, Greece

Dalton Trans., 2008, 6205-6210

DOI: 10.1039/B811143J
Received 01 Jul 2008, Accepted 15 Aug 2008
First published online 25 Sep 2008

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Abstract
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Compounds
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The synthesis and magnetic properties of three new members of a family of salicyaldoxime based [Mn₆] single-molecule magnets possessing new structural types, core topologies and Mn oxidation state distributions are reported. The isostructural complexes [Mn^III₆O₂(R-sao)₆(X)₂(EtOH)₆] (R = Et, X = Br (1); R = Me, X = I (2)) exhibit single-molecule magnet behaviour with spin Hamiltonian parameters S = 12, g = 1.98 and D = −0.36 cm⁻¹ in both cases. The hexametallic cluster [Mn^III₄Mn^IV₂O₂(OMe)₄(Et-sao)₆(MeOH)₂]·MeOH (3·MeOH) possesses a planar rod-like topology and a mixed valent [Mn^IV₄Mn^III₂] core, which is unprecedented in this family of [Mn₆] SMMs.

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Leigh F. Jones
Ross Inglis
Martyn E. Cochrane
Kevin Mason
Anna Collins
Simon Parsons
Spyros P. Perlepes
Euan K. Brechin

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New structural types and different oxidation levels in the family of Mn₆-oxime single-molecule magnets

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New structural types and different oxidation levels in the family of Mn6-oxime single-molecule magnets

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New structural types and different oxidation levels in the family of Mn₆-oxime single-molecule magnets