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The synthesis and magnetic properties of three new members of a family of salicyaldoxime based [Mn6] single-molecule magnets possessing new structural types, core topologies and Mnoxidation state distributions are reported. The isostructural complexes [MnIII6O2(R-sao)6(X)2(EtOH)6] (R = Et, X = Br (1); R = Me, X = I (2)) exhibit single-molecule magnet behaviour with spin Hamiltonian parameters S = 12, g = 1.98 and D = −0.36 cm−1 in both cases. The hexametallic cluster [MnIII4MnIV2O2(OMe)4(Et-sao)6(MeOH)2]·MeOH (3·MeOH) possesses a planar rod-like topology and a mixed valent [MnIV4MnIII2] core, which is unprecedented in this family of [Mn6] SMMs.
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