Vanadium(V) hydrazido(2−) thiolate imine alkoxide complexes†
Abstract
The reaction of (Me3Si)2TIP with V(NNMe2)(OAr)3 results in the production of V(NNMe2)(TIP)(OAr), where TIP is 2-((2-thiolatophenylimino)methylene)phenolate. The aryloxide is readily displaced by ISiMe3 to form an insoluble iodide complex formulated as V(NNMe2)(TIP)(I). The iodide was used to prepare three different complexes: [V(NNMe2)(TIP)(dmpe)]I, [V(NNMe2)(TIP)(Butbpy)][OTf], and [V(NNMe2)(TIP)(Butbpy)][SbF6]. The