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Issue 2, 2008
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Bridging the gap between solution and solid state studies in polyoxometalate chemistry: Discovery of a family of [V1M17]-based cages encapsulating two {VVO4} moieties

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Abstract

A family of polyoxometalates with the composition [H2V3M17O62]6– features a Dawson-like architecture containing two tetrahedral {VVO4} templates rather than main group hetero-anions ({PO4} or {SO4} etc.) typically associated with classical heteropolyacids, situated within a mixed-metal {MVI17VIVO54} cage and these clusters were first discovered using mass spectrometry.

Graphical abstract: Bridging the gap between solution and solid state studies in polyoxometalate chemistry: Discovery of a family of [V1M17]-based cages encapsulating two {VVO4} moieties

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Publication details

The article was received on 17 Sep 2007, accepted on 03 Oct 2007 and first published on 02 Nov 2007


Article type: Paper
DOI: 10.1039/B714285D
Citation: Dalton Trans., 2008, 214-221
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    Bridging the gap between solution and solid state studies in polyoxometalate chemistry: Discovery of a family of [V1M17]-based cages encapsulating two {VVO4} moieties

    H. N. Miras, D. Long, P. Kögerler and L. Cronin, Dalton Trans., 2008, 214
    DOI: 10.1039/B714285D

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