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Issue 42, 2008
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Encapsulated molecular catalysts in polysiloxane gels: ruthenium cluster-catalyzed isomerization of alkenes

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Abstract

Novel ruthenium-encapsulating polysiloxane gels are prepared by treatment of polymethylhydrosiloxane with diols in the presence of (μ3235-acenaphthylene)Ru3(CO)7, and act as reusable catalysts in the isomerization of alkenes without leakage of the catalyst species.

Graphical abstract: Encapsulated molecular catalysts in polysiloxane gels: ruthenium cluster-catalyzed isomerization of alkenes

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Publication details

The article was received on 11 Jun 2008, accepted on 11 Jul 2008 and first published on 17 Sep 2008


Article type: Communication
DOI: 10.1039/B809937E
Citation: Chem. Commun., 2008,0, 5321-5323
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    Encapsulated molecular catalysts in polysiloxane gels: ruthenium cluster-catalyzed isomerization of alkenes

    Y. Motoyama, M. Abe, K. Kamo, Y. Kosako and H. Nagashima, Chem. Commun., 2008, 0, 5321
    DOI: 10.1039/B809937E

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