Issue 36, 2008

Hydrous zinc halide-catalyzed aminosulfonation of hydrocarbons

Abstract

Benzylic and allylic hydrocarbons are selectively converted to the corresponding sulfonamides by a ZnBr2–H2O-catalyzed reaction with PhI[double bond, length as m-dash]NTs; saturated adamantane is aminosulfonated at the tertiary C–H bond.

Graphical abstract: Hydrous zinc halide-catalyzed aminosulfonation of hydrocarbons

Supplementary files

Article information

Article type
Communication
Submitted
08 Apr 2008
Accepted
16 Jun 2008
First published
05 Aug 2008

Chem. Commun., 2008, 4291-4293

Hydrous zinc halide-catalyzed aminosulfonation of hydrocarbons

B. Kalita, A. A. Lamar and K. M. Nicholas, Chem. Commun., 2008, 4291 DOI: 10.1039/B805783D

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