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Issue 24, 2008
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Hydrogen bonding directs the H2O2 oxidation of platinum(II) to a cis-dihydroxo platinum(IV) complex

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Abstract

The use of ligands with proximate hydrogen bonding substituents in the oxidation of platinum(II) dimethyl complexes with H2O2 leads to the exclusive formation of an unusual cis-dihydroxo platinum(IV) complex, which can dehydrate to form a trinuclear metalla-azacrown complex.

Graphical abstract: Hydrogen bonding directs the H2O2 oxidation of platinum(ii) to a cis-dihydroxo platinum(iv) complex

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Publication details

The article was received on 28 Feb 2008, accepted on 19 Mar 2008 and first published on 11 Apr 2008


Article type: Communication
DOI: 10.1039/B803370F
Citation: Chem. Commun., 2008,0, 2800-2802
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    Hydrogen bonding directs the H2O2 oxidation of platinum(II) to a cis-dihydroxo platinum(IV) complex

    R. A. Taylor, D. J. Law, G. J. Sunley, A. J. P. White and G. J. P. Britovsek, Chem. Commun., 2008, 0, 2800
    DOI: 10.1039/B803370F

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