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Issue 31, 2008
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Catalytic aerobic oxidation of substituted 8-methylquinolines in PdII-2,6-pyridinedicarboxylic acid systems

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Abstract

The ability of PdII complexes derived from 2,6-pyridinedicarboxylic acids to catalyze homogeneous regioselective aerobic oxidation of 5- and 6-substituted 8-methylquinolines in AcOH–Ac2O solution to produce corresponding 8-quinolylmethyl acetates in high yield was demonstrated; corresponding 8-quinoline carboxylic acids are minor reaction products.

Graphical abstract: Catalytic aerobic oxidation of substituted 8-methylquinolines in PdII-2,6-pyridinedicarboxylic acid systems

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Publication details

The article was received on 25 Feb 2008, accepted on 08 May 2008 and first published on 16 Jun 2008


Article type: Communication
DOI: 10.1039/B803156H
Citation: Chem. Commun., 2008,0, 3625-3627
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    Catalytic aerobic oxidation of substituted 8-methylquinolines in PdII-2,6-pyridinedicarboxylic acid systems

    J. Zhang, E. Khaskin, N. P. Anderson, P. Y. Zavalij and A. N. Vedernikov, Chem. Commun., 2008, 0, 3625
    DOI: 10.1039/B803156H

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