A rare ligand bridged ferromagnetically coupled MnIV3 complex with a ground spin state of S = 9/2

Thushan Pathmalingam; Serge I. Gorelsky; Tara J. Burchell; Anne-Catherine Bédard; André M. Beauchemin; Rodolphe Clérac; Muralee Murugesu

doi:10.1039/B802279H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A rare ligand bridged ferromagnetically coupled Mn^IV₃ complex with a ground spin state of S = 9/2†

Thushan Pathmalingam,^a Serge I. Gorelsky,^b Tara J. Burchell,^a Anne-Catherine Bédard,^ab André M. Beauchemin,*^ab Rodolphe Clérac^c and Muralee Murugesu*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of Ottawa, 10 Marie-Curie, Ottawa, ON, Canada
E-mail: m.murugesu@uottawa.ca, abeauche@uottawa.ca
Tel: +1 613 562 5800-2733

^b Centre for Catalysis Research and Innovation, University of Ottawa, 30 Marie-Curie, Ottawa, ON, Canada

^c Université Bordeaux 1, Centre de Recherche Paul Pascal, UPR-CNRS N°8641, 115 Av. A. Schweitzer, France

Abstract

An exclusively chelating ligand bridged high-valent [Mn^IV₃] complex has been synthesized, in which all Mn^IV ions are ferromagnetically-coupled to exhibit an S_T = 9/2 spin ground state.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/B802279H
Article type: Communication
Submitted: 11 Feb 2008
Accepted: 26 Mar 2008
First published: 16 Apr 2008

Download Citation

Chem. Commun., 2008, 2782-2784

Permissions

Request permissions

A rare ligand bridged ferromagnetically coupled Mn^IV₃ complex with a ground spin state of S = 9/2

T. Pathmalingam, S. I. Gorelsky, T. J. Burchell, A. Bédard, A. M. Beauchemin, R. Clérac and M. Murugesu, Chem. Commun., 2008, 2782 DOI: 10.1039/B802279H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications