Issue 25, 2008
From the journal:

Chemical Communications

An efficient synthesis of 2-vinylic cyclic 1,3-alkadienes via the Cp*Ru(ii)-catalyzed intermolecular coupling reactions of alkynes and cyclic allenes†

Tao Bai,a   Peng Xue,b   Li Zhang,b   Shengming Ma*a  and  Guochen Jia*b  

* Corresponding authors

a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, P. R. China
E-mail: masm@mail.sioc.ac.cn

b The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, P. R. China
E-mail: chjiag@ust.hk

Abstract

2-Vinylic cyclic 1,3-alkadienes can be obtained with moderate to good yields via the Cp*RuCl(PPh3)2-catalyzed coupling reaction of alkynes with cyclic allenes.

Graphical abstract: An efficient synthesis of 2-vinylic cyclic 1,3-alkadienes via the Cp*Ru(ii)-catalyzed intermolecular coupling reactions of alkynes and cyclic allenes

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Article information

DOI
https://doi.org/10.1039/B801500G
Article type
Communication
Submitted
28 Jan 2008
Accepted
11 Mar 2008
First published
16 Apr 2008

Chem. Commun., 2008, 2929-2931

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An efficient synthesis of 2-vinylic cyclic 1,3-alkadienes via the Cp*Ru(II)-catalyzed intermolecular coupling reactions of alkynes and cyclic allenes

T. Bai, P. Xue, L. Zhang, S. Ma and G. Jia, Chem. Commun., 2008, 2929 DOI: 10.1039/B801500G

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