Catalytic properties of MIL-101

Antje Henschel; Kristina Gedrich; Ralph Kraehnert; Stefan Kaskel

doi:10.1039/B718371B

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Catalytic properties of MIL-101†

Antje Henschel,^a Kristina Gedrich,^a Ralph Kraehnert^b and Stefan Kaskel*^a

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* Corresponding authors

^a Department of Inorganic Chemistry, Dresden University of Technology, Mommsenstr. 6, D-01069 Dresden, Germany
E-mail: stefan.kaskel@chemie.tu-dresden.de
Fax: +49-351-46337287
Tel: +49-351-46334885

^b Leibniz-Institute for Catalysis e.V. at the University of Rostock, Branch Berlin, Richard-Willstaetter-Str. 12, D-12489 Berlin, Germany

Abstract

A very high catalytic activity in the cyanosilylation reaction was observed for MIL-101, a chromium based metal–organic framework; moreover, MIL-101 is also a remarkably stable support for palladium in hydrogenation reactions, with significantly higher activity than e.g.palladium on activated carbon.

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Supplementary files

Synthetic details, powder X-ray diffraction patterns, nitrogen physisorption isotherms, additional catalytic data PDF (448K)

Article information

DOI: https://doi.org/10.1039/B718371B
Article type: Communication
Submitted: 28 Nov 2007
Accepted: 13 Jun 2008
First published: 01 Aug 2008

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Chem. Commun., 2008, 4192-4194

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Catalytic properties of MIL-101

A. Henschel, K. Gedrich, R. Kraehnert and S. Kaskel, Chem. Commun., 2008, 4192 DOI: 10.1039/B718371B

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Chemical Communications

Catalytic properties of MIL-101†

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Catalytic properties of MIL-101

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