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Issue 12, 2007
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The performance of poly(styrene)-block-poly(2-vinyl pyridine)-block-poly(styrene) triblock copolymers as pH-driven actuators

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Abstract

Poly(styrene)-block-poly(2-vinyl pyridine)-block-poly(styrene) (PS-b-P2VP-b-PS) triblock copolymers were synthesised by anionic polymerisation. Thick films were cast from solution and their structure analysed by small angle X-ray scattering (SAXS). Longer annealing times led to more ordered structures whereas short evaporation times effectively “lock” the polymer chains in a disordered state by vitrification. Well-ordered structures not only provide an isotropic network, which reduces localised stress within the material, but are also essential for fundamental studies of soft matter because their activity on the molecular scale must be analysed and understood prior to their use in technological applications. Well-characterised PS-b-P2VP-b-PS materials have been coupled to a pH-oscillating reaction and their potential application as responsive actuators is discussed.

Graphical abstract: The performance of poly(styrene)-block-poly(2-vinyl pyridine)-block-poly(styrene) triblock copolymers as pH-driven actuators

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Publication details

The article was received on 20 Jul 2007, accepted on 01 Oct 2007 and first published on 15 Oct 2007


Article type: Paper
DOI: 10.1039/B711125H
Citation: Soft Matter, 2007,3, 1506-1512
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    The performance of poly(styrene)-block-poly(2-vinyl pyridine)-block-poly(styrene) triblock copolymers as pH-driven actuators

    P. D. Topham, J. R. Howse, C. M. Fernyhough and A. J. Ryan, Soft Matter, 2007, 3, 1506
    DOI: 10.1039/B711125H

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