Issue 24, 2007
From the journal:

Dalton Transactions

The first metamagnetic thiocyanato-bridged one-dimensional nickel(ii) complex†‡

Shouvik Chattopadhyay,a   Michael G. B. Drew,b   Carmen Diazc  and  Ashutosh Ghosh*a  

* Corresponding authors

a Department of Chemistry, University College of Science, University of Calcutta, 92, A.P.C. Road, Kolkata, India
E-mail: ghosh_59@yahoo.com

b School of Chemistry, The University of Reading, PO Box 224, Whiteknights, Reading, UK

c Departament de Química Inorgánica, Universitat de Barcelona, Marti i Franques 1-11, Barcelona, Spain

Abstract

A novel single thiocyanato-bridged one-dimensional polymer, [NiL(NCS)(µ-NCS)]n (L = N1-(1-pyridin-2-yl-ethylidine)propane-1,3-diamine) has been synthesized and characterized by X-ray crystallography and a variable temperature magnetic study; the compound is a metamagnet with a Neél temperature (TN) of 3.5 K.

Graphical abstract: The first metamagnetic thiocyanato-bridged one-dimensional nickel(ii) complex

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Article information

DOI
https://doi.org/10.1039/B702814H
Article type
Communication
Submitted
23 Feb 2007
Accepted
02 May 2007
First published
14 May 2007

Dalton Trans., 2007, 2492-2494

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The first metamagnetic thiocyanato-bridged one-dimensional nickel(II) complex

S. Chattopadhyay, M. G. B. Drew, C. Diaz and A. Ghosh, Dalton Trans., 2007, 2492 DOI: 10.1039/B702814H

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