Synthesis and characterisation of a mixed-valence Mn13 complex with S6 symmetry by using 2-phenoxybenzoate

Alan Ferguson; Katrina Thomson; Andrew Parkin; Paul Cooper; Constantinos J. Milios; Euan K. Brechin; Mark Murrie

doi:10.1039/B615856K

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Synthesis and characterisation of a mixed-valence Mn₁₃ complex with S₆ symmetry by using 2-phenoxybenzoate†

Alan Ferguson,^a Katrina Thomson,^a Andrew Parkin,^a Paul Cooper,^b Constantinos J. Milios,^c Euan K. Brechin^c and Mark Murrie*^a

Author affiliations

* Corresponding authors

^a WestCHEM, Department of Chemistry, University of Glasgow, University Avenue, Glasgow, UK
E-mail: M.Murrie@chem.gla.ac.uk
Fax: +44 141 330 4888
Tel: +44 141 330 4486

^b School of Chemistry, University of Manchester, Oxford Road, Manchester, UK

^c EaStCHEM, School of Chemistry, University of Edinburgh, West Mains Road, UK

Abstract

The synthesis, structure and magnetic properties of [Mn₁₃O₈(OEt)₆(O₂CC₆H₄OPh)₁₂] are reported as the first example of a high nuclearity manganese complex with 2-phenoxybenzoate: the complex possesses S₆ symmetry and an S = 11/2 ground state.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/B615856K
Article type: Communication
Submitted: 31 Oct 2006
Accepted: 07 Dec 2006
First published: 18 Dec 2006

Download Citation

Dalton Trans., 2007, 728-730

Permissions

Request permissions

Synthesis and characterisation of a mixed-valence Mn₁₃ complex with S₆ symmetry by using 2-phenoxybenzoate

A. Ferguson, K. Thomson, A. Parkin, P. Cooper, C. J. Milios, E. K. Brechin and M. Murrie, Dalton Trans., 2007, 728 DOI: 10.1039/B615856K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions