Issue 46, 2007

Catalytically efficient palladium nanoparticles stabilized by “click” ferrocenyl dendrimers

Abstract

1,2,3-Ferrocenyl triazole ligands generated by click reactions in dendrimers bind Pd(OAc)2 with a systematic one-to-one stoichiometry as monitored by titration using the ferrocenyl redox sensor attached to the triazole ring, and the dendritic PdII complexes formed are best reduced by methanol to form palladium nanoparticles of designed types and sizes that show excellent efficiency and selectivity in olefin hydrogenation.

Graphical abstract: Catalytically efficient palladium nanoparticles stabilized by “click” ferrocenyl dendrimers

Supplementary files

Article information

Article type
Communication
Submitted
17 Jul 2007
Accepted
06 Sep 2007
First published
20 Sep 2007

Chem. Commun., 2007, 4946-4948

Catalytically efficient palladium nanoparticles stabilized by “click” ferrocenyl dendrimers

C. Ornelas, L. Salmon, J. Ruiz Aranzaes and D. Astruc, Chem. Commun., 2007, 4946 DOI: 10.1039/B710925C

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