Issue 28, 2007
From the journal:

Chemical Communications

Light-fluorous safety-catch arylgermanes – exceptionally robust, photochemically activated precursors for biaryl synthesis by Pd(0) catalysed cross-coupling†

Alan C. Spivey,*a   Chih-Chung Tseng,a   Joseph P. Hannah,a   Christopher J. G. Gripton,b   Paul de Fraine,c   Nigel J. Parrd  and  Jan J. Scicinskid  

* Corresponding authors

a Department of Chemistry, South Kensington Campus, Imperial College, London, UK
E-mail: a.c.spivey@imperial.ac.uk
Tel: +44 (0)20 75945841

b Department of Chemistry, University of Sheffield, Brook Hill, Sheffield, UK

c Discovery Chemistry, Syngenta, Jealott's Hill, Bracknell, Berkshire, UK

d Medicinal Chemistry, GlaxoSmithKline, Gunnelswood Road, Stevenage, Hertfordshire, UK

Abstract

A new class of arylgermane derivative that participate efficiently in Pd(0)-catalysed cross-coupling reactions with aryl bromides following photochemical activation is described.

Graphical abstract: Light-fluorous safety-catch arylgermanes – exceptionally robust, photochemically activated precursors for biaryl synthesis by Pd(0) catalysed cross-coupling

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Article information

DOI
https://doi.org/10.1039/B707517K
Article type
Communication
Submitted
18 May 2007
Accepted
12 Jun 2007
First published
21 Jun 2007

Chem. Commun., 2007, 2926-2928

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Light-fluorous safety-catch arylgermanes – exceptionally robust, photochemically activated precursors for biaryl synthesis by Pd(0) catalysed cross-coupling

A. C. Spivey, C. Tseng, J. P. Hannah, C. J. G. Gripton, P. de Fraine, N. J. Parr and J. J. Scicinski, Chem. Commun., 2007, 2926 DOI: 10.1039/B707517K

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