Issue 25, 2007
From the journal:

Chemical Communications

The first calibration of an aminiumyl radical ion clock: why N-cyclopropylanilines may be poor mechanistic probes for single electron transfer†

Xiangzhong Li,a   Michelle L. Grimm,a   Kazuo Igarashi,a   Neal Castagnoli, Jr.a  and  J. M. Tanko*a  

* Corresponding authors

a Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, VA, USA
E-mail: jtanko@vt.edu
Fax: +01 540 2313255
Tel: +01 540 2316687

Abstract

Using direct and indirect electrochemical methods, the rate constant for ring opening of the radical cation generated from N-cyclopropyl-N-methylaniline was found to be 4.1 × 104 s−1.

Graphical abstract: The first calibration of an aminiumyl radical ion clock: why N-cyclopropylanilines may be poor mechanistic probes for single electron transfer

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Article information

DOI
https://doi.org/10.1039/B702157G
Article type
Communication
Submitted
12 Feb 2007
Accepted
19 Mar 2007
First published
03 Apr 2007

Chem. Commun., 2007, 2648-2650

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The first calibration of an aminiumyl radical ion clock: why N-cyclopropylanilines may be poor mechanistic probes for single electron transfer

X. Li, M. L. Grimm, K. Igarashi, N. Castagnoli, Jr. and J. M. Tanko, Chem. Commun., 2007, 2648 DOI: 10.1039/B702157G

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