Issue 21, 2007
From the journal:

Chemical Communications

Factors influencing the selectivity in asymmetric oxidation of sulfides attached to nitrogen containing heterocycles†

Muthu Seenivasaperumal,a   Hans-Jürgen Federsel,b   Anne Ertanc  and  Kálmán J. Szabó*a  

* Corresponding authors

a Stockholm University, Arrhenius Laboratory, Department of Organic Chemistry, Sweden
E-mail: kalman@organ.su.se.

b Global Process R&D, AstraZeneca, Södertälje, Sweden

c Early Development, Pharmaceutical and Analytical R&D, AstraZeneca, Södertälje, Sweden

Abstract

Asymmetric oxidation of heterocyclic sulfides, including imidazole, benzimidazole, indole and pyrimidine derivatives, were studied using a tartrate/Ti(iOPr)4 catalyst system.

Graphical abstract: Factors influencing the selectivity in asymmetric oxidation of sulfides attached to nitrogen containing heterocycles

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Article information

DOI
https://doi.org/10.1039/B700860K
Article type
Communication
Submitted
18 Jan 2007
Accepted
12 Feb 2007
First published
02 Mar 2007

Chem. Commun., 2007, 2187-2189

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Factors influencing the selectivity in asymmetric oxidation of sulfides attached to nitrogen containing heterocycles

M. Seenivasaperumal, H. Federsel, A. Ertan and K. J. Szabó, Chem. Commun., 2007, 2187 DOI: 10.1039/B700860K

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