Issue 14, 2007

Single-crystal to single-crystal phase transitions of bis(N-phenylisonicotinamide)silver(i) nitrate reveal cooperativity properties in porous molecular materials

Abstract

Two single-crystal to single-crystal phase transitions in trans-[Ag(NPI)2](NO3)·2CH3OH (1a), (NPI = N-phenylisonicotinamide) were characterized with X-ray crystallography; the first transition is reversible and arises from a desolvation transition induced by vacuum and generated 1b; the second transition was induced by heat at 140 °C and generated 1c.

Graphical abstract: Single-crystal to single-crystal phase transitions of bis(N-phenylisonicotinamide)silver(i) nitrate reveal cooperativity properties in porous molecular materials

Supplementary files

Article information

Article type
Communication
Submitted
13 Nov 2006
Accepted
09 Jan 2007
First published
30 Jan 2007

Chem. Commun., 2007, 1433-1435

Single-crystal to single-crystal phase transitions of bis(N-phenylisonicotinamide)silver(I) nitrate reveal cooperativity properties in porous molecular materials

P. S. Mukherjee, N. Lopez, A. M. Arif, F. Cervantes-Lee and J. C. Noveron, Chem. Commun., 2007, 1433 DOI: 10.1039/B616502H

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