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Issue 6, 2007
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Asymmetric hydrogenation of quinolines with high substrate/catalyst ratio

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Abstract

The chiral diphosphinite ligand derived from (R)-1,1′-spirobiindane-7,7′-diol has been found to be highly effective in the Ir-catalyzed asymmetric hydrogenation of quinolines with high substrate/catalyst ratio (up to 5000) and high enantioselectivity (up to 94% ee).

Graphical abstract: Asymmetric hydrogenation of quinolines with high substrate/catalyst ratio

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Publication details

The article was received on 05 Oct 2006, accepted on 23 Oct 2006 and first published on 07 Nov 2006


Article type: Communication
DOI: 10.1039/B614446B
Citation: Chem. Commun., 2007,0, 613-615
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    Asymmetric hydrogenation of quinolines with high substrate/catalyst ratio

    W. Tang, S. Zhu, L. Xu, Q. Zhou, Q. Fan, H. Zhou, K. Lam and A. S. C. Chan, Chem. Commun., 2007, 0, 613
    DOI: 10.1039/B614446B

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