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Issue 6, 2007
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Fullerene acting as an electron donor in a donor–acceptor dyad to attain the long-lived charge-separated state by complexation with scandium ion

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Abstract

A long-lived charge-separated (CS) state of fullerene–trinitrofluorenone linked dyad in which fullerene acts as an electron donor is formed by photoinduced electron transfer from C60 to TNF in the presence of Sc(OTf)3; the CS lifetime is determined as 23 ms in PhCN at 298 K.

Graphical abstract: Fullerene acting as an electron donor in a donor–acceptor dyad to attain the long-lived charge-separated state by complexation with scandium ion

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Publication details

The article was received on 01 Sep 2006, accepted on 27 Oct 2006 and first published on 10 Nov 2006


Article type: Communication
DOI: 10.1039/B612613H
Citation: Chem. Commun., 2007,0, 589-591
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    Fullerene acting as an electron donor in a donor–acceptor dyad to attain the long-lived charge-separated state by complexation with scandium ion

    K. Ohkubo, J. Ortiz, L. Martín-Gomis, F. Fernández-Lázaro, Á. Sastre-Santos and S. Fukuzumi, Chem. Commun., 2007, 0, 589
    DOI: 10.1039/B612613H

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