Sulfanyl radical promoted C4′–C5′ bond scission of 5′-oxo-3′,4′-didehydro-2′,3′-dideoxynucleosides†
Abstract
Treatment of C5′-aldehydes 4a,b under mildly basic conditions leads to the formation of 3′,4′-didehydroaldehydes 1a,b and
* Corresponding authors
a ISOF, Consiglio Nazionale delle Ricerche, Via P. Gobetti 101, Bologna, Italy
b
Dipartimento di Chimica Organica “A. Mangini”, Università di Bologna, Viale Risorgimento 4, Bologna, Italy
E-mail:
montevec@ms.fci.unibo.it
Treatment of C5′-aldehydes 4a,b under mildly basic conditions leads to the formation of 3′,4′-didehydroaldehydes 1a,b and
M. L. Navacchia and P. C. Montevecchi, Org. Biomol. Chem., 2006, 4, 3754 DOI: 10.1039/B609995E
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