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The appearance of structurally diverse fluorinating reagents displaying a large spectrum of reactivity has been critical to the development of the catalytic asymmetric fluorination processes known to date. In this article, we discuss how this area of research emerged and which strategies have allowed for the successful development of both nucleophilic and electrophilic catalytic enantioselective fluorinations. We also present the fundamental understanding of catalytic activity and enantioselectivity for the most efficient processes and highlight the first synthetic application with the preparation of a complex fluorinated target.
A review, with 46 references, on the emergence of catalytic asymmetric fluorinations and the strategies that have allowed the development of nucleophilic and electrophilic catalytic enantioselective fluorinations.
A review, with 46 references, on how the research area of catalytic asymmetric fluorinations emerged and which strategies have allowed for the successful development of both nucleophilic and electrophilic catalytic enantioselective fluorinations.
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Organic & Biomolecular Chemistry
- Information Point