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Issue 13, 2006
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A structural and magnetic study of organolanthanide(III) amides

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Abstract

The syntheses, structures and magnetic properties of the series of dimeric organolanthanide(III) amides [Cp2Ln{2-NH-4,6-Me2pm}]2 [Ln = Nd (1), Gd (2), Dy (3), Yb (4) and pm = pyrimidine], which are formed from the deprotonation of 2-amino-4,6-dimethylpyrimidine by the corresponding lanthanide tris-cyclopentadienide, are reported. The synthesis and structure of [{Cp2Yb(2-NH-4-MeO-6-MeOpm)23-O)(YbCp)] (5), formed in a similar deprotonation reaction but in the presence of adventitious water, is also reported.

Graphical abstract: A structural and magnetic study of organolanthanide(iii) amides

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Publication details

The article was received on 12 Oct 2005, accepted on 29 Nov 2005 and first published on 14 Dec 2005


Article type: Paper
DOI: 10.1039/B514470A
Citation: Dalton Trans., 2006,0, 1660-1666
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    A structural and magnetic study of organolanthanide(III) amides

    R. A. Layfield, A. Bashall, M. McPartlin, J. M. Rawson and D. S. Wright, Dalton Trans., 2006, 0, 1660
    DOI: 10.1039/B514470A

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