Palladium complexes with Pd→B dative bonds: Analysis of the bonding in the palladaboratrane compound [κ4-B(mimBut)3]Pd(PMe3)

Keliang Pang; Stephanie M. Quan; Gerard Parkin

doi:10.1039/B611654J

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Palladium complexes with Pd→B dative bonds: Analysis of the bonding in the palladaboratrane compound [κ⁴-B(mim^{Bu^t})₃]Pd(PMe₃)†

Keliang Pang,^a Stephanie M. Quan^a and Gerard Parkin*^a

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* Corresponding authors

^a Department of Chemistry, Columbia University in the City of New York, USA
E-mail: parkin@columbia.edu

Abstract

The dinuclear complex {[μ-κ¹,κ³-B(mim^{Bu^t})₃]Pd}₂, which features a Pd→B dative bond, may be obtained by the reaction of [Tm^{Bu^t}]K with Pd(OAc)₂; treatment of {[μ-κ¹,κ³-B(mim^{Bu^t})₃]Pd}₂ with PMe₃ affords the mononuclear boratrane derivative [κ⁴-B(mim^{Bu^t})₃]Pd(PMe₃), for which a molecular orbital analysis indicates that the palladium center possesses a d⁸ configuration.

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Article information

DOI: https://doi.org/10.1039/B611654J
Article type: Communication
Submitted: 14 Aug 2006
Accepted: 15 Sep 2006
First published: 12 Oct 2006

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Chem. Commun., 2006, 5015-5017

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Palladium complexes with Pd→B dative bonds: Analysis of the bonding in the palladaboratrane compound [κ⁴-B(mim^{Bu^t})₃]Pd(PMe₃)

K. Pang, S. M. Quan and G. Parkin, Chem. Commun., 2006, 5015 DOI: 10.1039/B611654J

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