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Issue 47, 2006
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A simple asymmetric organocatalytic approach to optically active cyclohexenones

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Abstract

Optically active 2,5-disubstituted-cyclohexen-2-one derivatives have been prepared in a one-pot process consisting of five reaction steps: an organocatalytic asymmetric conjugated addition of β-ketoesters to α,β-unsaturated aldehydes that proceeds in aqueous solutions or under solvent-free conditions has been implemented in a multi-step process.

Graphical abstract: A simple asymmetric organocatalytic approach to optically active cyclohexenones

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Publication details

The article was received on 08 Aug 2006, accepted on 18 Sep 2006 and first published on 05 Oct 2006


Article type: Communication
DOI: 10.1039/B611366D
Citation: Chem. Commun., 2006,0, 4928-4930
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    A simple asymmetric organocatalytic approach to optically active cyclohexenones

    A. Carlone, M. Marigo, C. North, A. Landa and K. A. Jørgensen, Chem. Commun., 2006, 0, 4928
    DOI: 10.1039/B611366D

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