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Issue 39, 2006
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Enantioselective nitroaldol (Henry) reaction using copper(II) complexes of (−)-sparteine

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Abstract

The dichloro[(−)-sparteine-N,N′]copper(II) complex provides Henry adducts with high enantioselectivities (73–97% ee) in Henry reaction between nitromethane and various aldehydes.

Graphical abstract: Enantioselective nitroaldol (Henry) reaction using copper(ii) complexes of (−)-sparteine

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Publication details

The article was received on 17 Jul 2006, accepted on 29 Aug 2006 and first published on 14 Sep 2006


Article type: Communication
DOI: 10.1039/B610203D
Citation: Chem. Commun., 2006,0, 4066-4068
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    Enantioselective nitroaldol (Henry) reaction using copper(II) complexes of (−)-sparteine

    H. Maheswaran, K. L. Prasanth, G. G. Krishna, K. Ravikumar, B. Sridhar and M. L. Kantam, Chem. Commun., 2006, 0, 4066
    DOI: 10.1039/B610203D

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