Issue 41, 2006

The rapid photomediated alkenylation of 2-alkyl-1,3-dioxolanes with alkynes: a stereoelectronically assisted chain reaction

Abstract

The photomediated reaction of alkynes such as DMAD with 1,3-dioxolanes leads to remarkably rapid alkenylation; evidence is presented that these reactions occur via a chain mechanism.

Graphical abstract: The rapid photomediated alkenylation of 2-alkyl-1,3-dioxolanes with alkynes: a stereoelectronically assisted chain reaction

Article information

Article type
Communication
Submitted
26 Jun 2006
Accepted
02 Aug 2006
First published
29 Aug 2006

Chem. Commun., 2006, 4300-4302

The rapid photomediated alkenylation of 2-alkyl-1,3-dioxolanes with alkynes: a stereoelectronically assisted chain reaction

N. W. A. Geraghty and A. Lally, Chem. Commun., 2006, 4300 DOI: 10.1039/B608979H

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