Issue 16, 2006
From the journal:

Chemical Communications

Formation of aluminacyclobutenes via carbon monoxide and isocyanide insertion

Xiaofei Li,a   Chengbao Ni,a   Haibing Songa  and  Chunming Cui*a  

* Corresponding authors

a State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, P. R. China
E-mail: cmcui@nankai.edu.cn
Fax: +86-22-23503461
Tel: +86-22-23503461

Abstract

Reaction of LAl[η2-(CSiMe3)2] (L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3) with carbon monoxide and tert-butyl isocyanide afforded unique AlC3 aluminacyclobutenes via insertion into one of the aluminium–carbon bonds.

Graphical abstract: Formation of aluminacyclobutenes via carbon monoxide and isocyanide insertion

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Article information

DOI
https://doi.org/10.1039/B601056C
Article type
Communication
Submitted
23 Jan 2006
Accepted
03 Mar 2006
First published
15 Mar 2006

Chem. Commun., 2006, 1763-1765

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Formation of aluminacyclobutenes via carbon monoxide and isocyanide insertion

X. Li, C. Ni, H. Song and C. Cui, Chem. Commun., 2006, 1763 DOI: 10.1039/B601056C

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