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Issue 7, 2006
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Novel weak coordination to silylium ions: formation of nearly linear Si–H–Si bonds

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Abstract

The weakly coordinating carborane anion in ion-like trialkylsilyl species R3Si(CHB11Cl11) can be displaced by nucleophiles as weak as ortho-dichlorobenzene, SO2 and trialkylsilanes, the latter forming nearly linear hydride bridges in R3Si–H–SiR3+ cations.

Graphical abstract: Novel weak coordination to silylium ions: formation of nearly linear Si–H–Si bonds

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Publication details

The article was received on 09 Aug 2005, accepted on 01 Dec 2005 and first published on 05 Jan 2006


Article type: Communication
DOI: 10.1039/B511344J
Citation: Chem. Commun., 2006, 767-769
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    Novel weak coordination to silylium ions: formation of nearly linear Si–H–Si bonds

    S. P. Hoffmann, T. Kato, F. S. Tham and C. A. Reed, Chem. Commun., 2006, 767
    DOI: 10.1039/B511344J

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