Issue 14, 2006
From the journal:

Chemical Communications

Photoinduced phase transition of coordinationally unsaturated d9 metal centers within the thermal hysteresis of the spin exchange interaction

Panče Naumov,*abc   Kenji Sakurai,d   Toru Asaka,e   Alexei A. Belik,a   Shin-ichi Adachi,cf   Junichi Takahashicf  and  Shin-ya Koshiharacfg  

* Corresponding authors

a ICYS, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki, Japan
E-mail: naumov.pance@nims.go.jp
Fax: +81-29-860-4706
Tel: +81-29-851-3354 (8572)

b Institute of Chemistry, Faculty of Science, Sts. Cyril and Methodius University, Arhimedova 5, Skopje, Macedonia

c Exploratory Research for Advanced Technology (ERATO), 4-1-8 Honcho, Kawaguchi, Japan

d X-ray Physics Group, MEL, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki, Japan
Fax: +81-29-860-4706
Tel: +81-29-851-3354 (8572)

e HVEMS, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki, Japan
Fax: +81-29-860-4706
Tel: +81-29-851-3354 (8572)

f High Energy Accelerator Research Organization (KEK), 1-1 Oho, Tsukuba, Ibaraki, Japan

g Department of Materials Science, Tokyo Institute of Technology, 1-12-1 O-okayama, Meguro, Tokyo, Japan

Abstract

Diffraction evidence is presented that the structure of one-dimensional arrays of strained, coordinationally unsaturated d9 pseudo-Jahn–Teller centers is affected by excitation of the LMCT bands within the hysteresis region of the low-temperature ferromagnetic-to-antiferromagnetic phase transition.

Graphical abstract: Photoinduced phase transition of coordinationally unsaturated d9 metal centers within the thermal hysteresis of the spin exchange interaction

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Article information

DOI
https://doi.org/10.1039/B516513J
Article type
Communication
Submitted
22 Nov 2005
Accepted
27 Jan 2006
First published
22 Feb 2006

Chem. Commun., 2006, 1491-1493

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Photoinduced phase transition of coordinationally unsaturated d9 metal centers within the thermal hysteresis of the spin exchange interaction

P. Naumov, K. Sakurai, T. Asaka, A. A. Belik, S. Adachi, J. Takahashi and S. Koshihara, Chem. Commun., 2006, 1491 DOI: 10.1039/B516513J

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