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Issue 6, 2005
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Fluoroaryl-substituted aminoalane dimers: syntheses and structures

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Abstract

Six dimeric aminoalanes of formula [Me2Al-µ-N(H)ArF]2 (ArF = 4-C6H4F (1), 2-C6H4F (2), 3,5-C6H3F2 (3), 2,3,4,5-C6HF4 (4), 2,3,5,6-C6HF4 (5) and C6F5 (6)) have been prepared by treatment of the appropriate fluoroaniline with AlMe3 in toluene solution at 25 °C. The structures of 1–6 were determined by X-ray crystallography.

Graphical abstract: Fluoroaryl-substituted aminoalane dimers: syntheses and structures

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Publication details

The article was received on 22 Nov 2004, accepted on 27 Jan 2005 and first published on 10 Feb 2005


Article type: Paper
DOI: 10.1039/B417652A
Citation: Dalton Trans., 2005,0, 1019-1022
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    Fluoroaryl-substituted aminoalane dimers: syntheses and structures

    P. Shukla, A. H. Cowley, J. N. Jones, J. C. Gordon and B. L. Scott, Dalton Trans., 2005, 0, 1019
    DOI: 10.1039/B417652A

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