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Issue 47, 2005
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[LnIIAlIII2(alkyl)8]x: donor addition instead of donor-induced cleavage

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Abstract

(SmAl2Me8)x and (SmAl2Et8)x are obtained via a silylamide elimination reaction from Sm[N(SiMe3)2]2(THF)2 and excess AlR3 (R = Me, Et); (LnAl2Et8)x (Ln = Sm, Yb) react with THF, pyridine, and 1,10-phenanthroline to form the first donor adducts of homoleptic peralkylated Ln–Al heterobimetallic complexes.

Graphical abstract: [LnIIAlIII2(alkyl)8]x: donor addition instead of donor-induced cleavage

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Publication details

The article was received on 25 Aug 2005, accepted on 21 Sep 2005 and first published on 21 Oct 2005


Article type: Communication
DOI: 10.1039/B512047K
Citation: Chem. Commun., 2005,0, 5922-5924
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    [LnIIAlIII2(alkyl)8]x: donor addition instead of donor-induced cleavage

    M. G. Schrems, H. M. Dietrich, K. W. Törnroos and R. Anwander, Chem. Commun., 2005, 0, 5922
    DOI: 10.1039/B512047K

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