Issue 45, 2005
From the journal:

Chemical Communications

Rhodium-catalysed 1,4-addition of diarylindium hydroxides to α,β-unsaturated carbonyl compounds

Tomoya Miuraa  and  Masahiro Murakami*a  

* Corresponding authors

a Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto, Japan
E-mail: murakami@sbchem.kyoto-u.ac.jp
Fax: +81 75 383 2748
Tel: +81 75 383 2747

Abstract

Diarylindium(III) hydroxides react with α,β-unsaturated carbonyl compounds in the presence of a rhodium catalyst to afford the 1,4-addition products in high yield. This reaction demonstrates the utility of diarylindium(III) hydroxide as an aryl source with rhodium catalysts.

Graphical abstract: Rhodium-catalysed 1,4-addition of diarylindium hydroxides to α,β-unsaturated carbonyl compounds

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Article information

DOI
https://doi.org/10.1039/B511779H
Article type
Communication
Submitted
19 Aug 2005
Accepted
15 Sep 2005
First published
13 Oct 2005

Chem. Commun., 2005, 5676-5677

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Rhodium-catalysed 1,4-addition of diarylindium hydroxides to α,β-unsaturated carbonyl compounds

T. Miura and M. Murakami, Chem. Commun., 2005, 5676 DOI: 10.1039/B511779H

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