Issue 39, 2005
From the journal:

Chemical Communications

Divergent coordination mode of magnesium and zinc alkyls supported by the bifunctional pyrrolylaldiminato ligand

Janusz Lewiński,*a   Maciej Dranka,a   Izabela Kraszewska,a   Witold Śliwińskia  and  Iwona Justyniakb  

* Corresponding authors

a Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland
E-mail: lewin@ch.pw.edu.pl

b Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland

Abstract

The first magnesium and zinc alkyls derived from N-(iso-propyl)-pyrrolylaldimine have been synthesised and structurally characterised: both tBuM(N,N′)-type compounds exist as three-coordinate monomers in benzene solution, but in the solid state the magnesium complex is a centrosymmetric dimer with Mg2(μ-N)2 bridges, whereas the zinc complex is a Zn⋯π bonded dimer with a π-coordinated pyrrole unit.

Graphical abstract: Divergent coordination mode of magnesium and zinc alkyls supported by the bifunctional pyrrolylaldiminato ligand

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Article information

DOI
https://doi.org/10.1039/B509669C
Article type
Communication
Submitted
08 Jul 2005
Accepted
11 Aug 2005
First published
07 Sep 2005

Chem. Commun., 2005, 4935-4937

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Divergent coordination mode of magnesium and zinc alkyls supported by the bifunctional pyrrolylaldiminato ligand

J. Lewiński, M. Dranka, I. Kraszewska, W. Śliwiński and I. Justyniak, Chem. Commun., 2005, 4935 DOI: 10.1039/B509669C

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