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Issue 37, 2005
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Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

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Abstract

In the presence of moderately strong acids in CH3CN, cobalt complexes with BF2-bridged diglyoxime ligands are active catalysts for the reduction of protons to H2 at potentials as positive as −0.28 V vs. SCE.

Graphical abstract: Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

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Publication details

The article was received on 28 Jun 2005, accepted on 29 Jul 2005 and first published on 23 Aug 2005


Article type: Communication
DOI: 10.1039/B509188H
Citation: Chem. Commun., 2005, 4723-4725
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    Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

    X. Hu, B. M. Cossairt, B. S. Brunschwig, N. S. Lewis and J. C. Peters, Chem. Commun., 2005, 4723
    DOI: 10.1039/B509188H

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