Issue 29, 2005
From the journal:

Chemical Communications

Liquid-phase oxidation of alkylaromatics by a H-atom transfer mechanism with a new heterogeneous CoSBA-15 catalyst†‡

Richard L. Brutchey,ab   Ian J. Drake,c   Alexis T. Bellc  and  T. Don Tilley*ab  

* Corresponding authors

a Department of Chemistry, University of California, Berkeley, Berkeley, California, USA
E-mail: tdtilley@berkeley.edu
Tel: 1 (510) 642-8939

b the Chemical Sciences Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California, USA

c Department of Chemical Engineering, University of California, Berkeley, Berkeley, California, USA

Abstract

A new pseudo-tetrahedral Co(II) complex has been grafted onto the surface of SBA-15 and successfully utilized for the catalytic oxidization of alkylaromatic substrates with tert-butyl hydroperoxide (TBHP) via an H-atom transfer mechanism.

Graphical abstract: Liquid-phase oxidation of alkylaromatics by a H-atom transfer mechanism with a new heterogeneous CoSBA-15 catalyst

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Article information

DOI
https://doi.org/10.1039/B506426K
Article type
Communication
Submitted
10 May 2005
Accepted
10 Jun 2005
First published
04 Jul 2005

Chem. Commun., 2005, 3736-3738

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Liquid-phase oxidation of alkylaromatics by a H-atom transfer mechanism with a new heterogeneous CoSBA-15 catalyst

R. L. Brutchey, I. J. Drake, A. T. Bell and T. D. Tilley, Chem. Commun., 2005, 3736 DOI: 10.1039/B506426K

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