Issue 27, 2005
From the journal:

Chemical Communications

Square planar bis(imino)pyridine iron halide and alkyl complexes†‡

Marco W. Bouwkamp,a   Suzanne C. Bart,a   Eric J. Hawrelak,§a   Ryan J. Trovitch,a   Emil Lobkovskya  and  Paul J. Chirik*a  

* Corresponding authors

a Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, NY, USA
E-mail: pc92@cornell.edu
Fax: 607-255-4137
Tel: 607-254-4538

Abstract

Square planar iron methyl complexes containing bis(imino)pyridine (PDI) ligands have been prepared by reductive alkylation of the corresponding ferrous dichloride; dialkylation is observed upon treatment with a larger alkyl lithium.

Graphical abstract: Square planar bis(imino)pyridine iron halide and alkyl complexes

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Article information

DOI
https://doi.org/10.1039/B504063A
Article type
Communication
Submitted
20 Mar 2005
Accepted
28 Apr 2005
First published
27 May 2005

Chem. Commun., 2005, 3406-3408

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Square planar bis(imino)pyridine iron halide and alkyl complexes

M. W. Bouwkamp, S. C. Bart, E. J. Hawrelak, R. J. Trovitch, E. Lobkovsky and P. J. Chirik, Chem. Commun., 2005, 3406 DOI: 10.1039/B504063A

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