Issue 22, 2005
From the journal:

Chemical Communications

Intramolecular nucleophilic addition of an organorhodium(i) to a nitrile†

Tomoya Miura,a   Hiroki Nakazawaa  and  Masahiro Murakami*a  

* Corresponding authors

a Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto, Japan
E-mail: murakami@sbchem.kyoto-u.ac.jp
Fax: +81 75 383 2748
Tel: +81 75 383 2747

Abstract

Nucleophilic addition of an organorhodium(I) to a cyano group has been observed for the first time in the rhodium-catalysed reaction of cyano-substituted alkynes with arylboronic acids. The higher reactivity of a cyano group relative to an alkoxycarbonyl group toward an organorhodium(I) species is demonstrated by an intramolecular example.

Graphical abstract: Intramolecular nucleophilic addition of an organorhodium(i) to a nitrile

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Article information

DOI
https://doi.org/10.1039/B503686K
Article type
Communication
Submitted
11 Mar 2005
Accepted
08 Apr 2005
First published
22 Apr 2005

Chem. Commun., 2005, 2855-2856

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Intramolecular nucleophilic addition of an organorhodium(I) to a nitrile

T. Miura, H. Nakazawa and M. Murakami, Chem. Commun., 2005, 2855 DOI: 10.1039/B503686K

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