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Issue 27, 2005
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Monometallic and heterobimetallic azanickellacycles as ethylene polymerization catalysts

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Abstract

The azanickellacyclic complex (1) produced by trimerization of an isocyanide on the nickel atom is found to be a new ethylene polymerization catalyst; catalytic activity is increased by incorporation of the second metal to a diimino moiety of 1 leading to formation of heterobimetallic complexes.

Graphical abstract: Monometallic and heterobimetallic azanickellacycles as ethylene polymerization catalysts

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Publication details

The article was received on 01 Mar 2005, accepted on 26 Apr 2005 and first published on 31 May 2005


Article type: Communication
DOI: 10.1039/B502942B
Citation: Chem. Commun., 2005,0, 3409-3411
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    Monometallic and heterobimetallic azanickellacycles as ethylene polymerization catalysts

    M. Tanabiki, K. Tsuchiya, Y. Motoyama and H. Nagashima, Chem. Commun., 2005, 0, 3409
    DOI: 10.1039/B502942B

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