Issue 27, 2005
From the journal:

Chemical Communications

Monometallic and heterobimetallic azanickellacycles as ethylene polymerization catalysts†

Masao Tanabiki,ab   Kazuhiro Tsuchiya,b   Yukihiro Motoyamabc  and  Hideo Nagashima*bc  

* Corresponding authors

a TOSOH Corporation, 1-8, Kasumi, Yokkaichi, Mie, Japan

b Graduate School of Engineering Sciences, Kyushu University, Kasuga, Fukuoka, Japan

c Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, Fukuoka, Japan
E-mail: nagasima@cm.kyushu-u.ac.jp
Fax: +81-92-583-7819
Tel: +81-92-583-7819

Abstract

The azanickellacyclic complex (1) produced by trimerization of an isocyanide on the nickel atom is found to be a new ethylene polymerization catalyst; catalytic activity is increased by incorporation of the second metal to a diimino moiety of 1 leading to formation of heterobimetallic complexes.

Graphical abstract: Monometallic and heterobimetallic azanickellacycles as ethylene polymerization catalysts

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Article information

DOI
https://doi.org/10.1039/B502942B
Article type
Communication
Submitted
01 Mar 2005
Accepted
26 Apr 2005
First published
31 May 2005

Chem. Commun., 2005, 3409-3411

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Monometallic and heterobimetallic azanickellacycles as ethylene polymerization catalysts

M. Tanabiki, K. Tsuchiya, Y. Motoyama and H. Nagashima, Chem. Commun., 2005, 3409 DOI: 10.1039/B502942B

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