Issue 21, 2005
From the journal:

Chemical Communications

Tetraalkynyl calix[4]arenes with advanced NLO properties†

Gunther Hennrich,*a   M. Teresa Murillo,a   Pilar Prados,a   Kai Song,b   Inge Asselberghs,b   Koen Clays,*b   André Persoons,b   Jordi Benet-Buchholzc  and  Javier de Mendozac  

* Corresponding authors

a Departamento de Química Orgánica, Universidad Autónoma de Madrid, Cantoblanco, Madrid, Spain
E-mail: gunther.hennrich@uam.es
Fax: 34 91-497 3966
Tel: 34 91-497 3879

b Department of Chemistry, University of Leuven, Celestijnenlaan 200 D, Leuven, Belgium

c Institute of Chemical Research of Catalonia (ICIQ), Avgda. Països Catalans s/n, Tarragona, Spain

Abstract

Rigid, highly conjugated tetraalkynyl-calix[4]arenes synthesised via Sonogashira coupling give rise to improved second-order hyperpolarizability values as determined by hyper-Rayleigh scattering—a technique that in addition to X-ray crystallography also allows for the conformational analysis of the calixarene structures in solution.

Graphical abstract: Tetraalkynyl calix[4]arenes with advanced NLO properties

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B502045J
Article type
Communication
Submitted
10 Feb 2005
Accepted
24 Mar 2005
First published
13 Apr 2005

Chem. Commun., 2005, 2747-2749

Permissions

Request permissions

Tetraalkynyl calix[4]arenes with advanced NLO properties

G. Hennrich, M. T. Murillo, P. Prados, K. Song, I. Asselberghs, K. Clays, A. Persoons, J. Benet-Buchholz and J. de Mendoza, Chem. Commun., 2005, 2747 DOI: 10.1039/B502045J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements