Selective O2 oxidation of air-sensitive lanthanocene thiolates and thioether chelate

Xigeng Zhou; Ming Zhu; Libei Zhang; Zhenyu Zhu; Chengfu Pi; Zhen Pang; Linhong Weng; Ruifang Cai

doi:10.1039/B417609J

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Selective O₂oxidation of air-sensitive lanthanocene thiolates and thioether chelate†

Xigeng Zhou,*^ab Ming Zhu,^a Libei Zhang,^a Zhenyu Zhu,^a Chengfu Pi,^a Zhen Pang,^a Linhong Weng^a and Ruifang Cai^a

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* Corresponding authors

^a Department of Chemistry, Molecular Catalysis and Innovative Material Laboratory, Fudan University, People's Republic of China
E-mail: xgzhou@fudan.edu.cn.
Fax: +86 21 65643769
Tel: +86 21 65641740

^b State Key Laboratory of Organometallic Chemistry, Shanghai 200032, People's Republic of China

Abstract

Two unusual regioselective O₂ oxidation reactions of air-sensitive lanthanocene thiolates and a thioether chelate are described, revealing a novel oxygenation pattern of thiolate ligands.

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Article information

DOI: https://doi.org/10.1039/B417609J
Article type: Communication
Submitted: 19 Nov 2004
Accepted: 04 Mar 2005
First published: 15 Mar 2005

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Chem. Commun., 2005, 2342-2344

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Selective O₂ oxidation of air-sensitive lanthanocene thiolates and thioether chelate

X. Zhou, M. Zhu, L. Zhang, Z. Zhu, C. Pi, Z. Pang, L. Weng and R. Cai, Chem. Commun., 2005, 2342 DOI: 10.1039/B417609J

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Chemical Communications