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Issue 9, 2005
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Polyoxoanions functionalized by diorganotin groups: the tetrameric, chiral tungstoarsenate(III), [{Sn(CH3)2(H2O)}2{Sn(CH3)2}As3(α-AsW9O33)4]21−

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Abstract

The tetrameric, hybrid organic–inorganic tungstoarsenate(III) [{Sn(CH3)2(H2O)}2{Sn(CH3)2}As3(α-AsW9O33)4]21− (1) is composed of four (B-α-AsW9O33) fragments that are linked by three dimethyltin groups and three As(III) atoms resulting in an unprecedented, chiral polyoxoanion assembly with C1 symmetry.

Graphical abstract: Polyoxoanions functionalized by diorganotin groups: the tetrameric, chiral tungstoarsenate(iii), [{Sn(CH3)2(H2O)}2{Sn(CH3)2}As3(α-AsW9O33)4]21−

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Publication details

The article was received on 14 Oct 2004, accepted on 07 Dec 2004 and first published on 18 Jan 2005


Article type: Communication
DOI: 10.1039/B415901B
Citation: Chem. Commun., 2005,0, 1191-1193
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    Polyoxoanions functionalized by diorganotin groups: the tetrameric, chiral tungstoarsenate(III), [{Sn(CH3)2(H2O)}2{Sn(CH3)2}As3(α-AsW9O33)4]21−

    F. Hussain and U. Kortz, Chem. Commun., 2005, 0, 1191
    DOI: 10.1039/B415901B

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