Issue 11, 2005

Unexpected conversion of a hexacyanometallate to a homoleptic nitrile complex with triphenylborane substituents

Abstract

The homoleptic, triphenylborane adduct of the hexacyanochromate anion was structurally characterized and found to be a product in which all six cyanide ligands have undergone isomerization to nitrile groups.

Graphical abstract: Unexpected conversion of a hexacyanometallate to a homoleptic nitrile complex with triphenylborane substituents

Supplementary files

Article information

Article type
Communication
Submitted
17 Sep 2004
Accepted
09 Dec 2004
First published
26 Jan 2005

Chem. Commun., 2005, 1417-1419

Unexpected conversion of a hexacyanometallate to a homoleptic nitrile complex with triphenylborane substituents

E. J. Schelter, M. Shatruk, R. A. Heintz, J. R. Galán-Mascarós and K. R. Dunbar, Chem. Commun., 2005, 1417 DOI: 10.1039/B414262D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements