Issue 11, 2005
From the journal:

Chemical Communications

Unexpected conversion of a hexacyanometallate to a homoleptic nitrile complex with triphenylborane substituents

Eric J. Schelter,a   Mikhail Shatruk,a   Robert A. Heintz,a   José Ramón Galán-Mascarósa  and  Kim R. Dunbar*a  

* Corresponding authors

a Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, USA
E-mail: dunbar@mail.chem.tamu.edu
Fax: +1-979-845-7177
Tel: +1-979-845-5235

Abstract

The homoleptic, triphenylborane adduct of the hexacyanochromate anion was structurally characterized and found to be a product in which all six cyanide ligands have undergone isomerization to nitrile groups.

Graphical abstract: Unexpected conversion of a hexacyanometallate to a homoleptic nitrile complex with triphenylborane substituents

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Article information

DOI
https://doi.org/10.1039/B414262D
Article type
Communication
Submitted
17 Sep 2004
Accepted
09 Dec 2004
First published
26 Jan 2005

Chem. Commun., 2005, 1417-1419

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Unexpected conversion of a hexacyanometallate to a homoleptic nitrile complex with triphenylborane substituents

E. J. Schelter, M. Shatruk, R. A. Heintz, J. R. Galán-Mascarós and K. R. Dunbar, Chem. Commun., 2005, 1417 DOI: 10.1039/B414262D

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