Issue 1, 2005

Synthesis and structural characterization of highly chlorinated C70, C70Cl28

Abstract

Chlorination of [70]fullerene with SbCl5, VCl4 or PCl5 yielded C70Cl28 comprising three isomers, all containing four isolated benzenoid rings in the fullerene cage. This demonstrates, for the first time for C70 derivatives, a stabilization effect due to planar aromaticity.

Graphical abstract: Synthesis and structural characterization of highly chlorinated C70, C70Cl28

Article information

Article type
Communication
Submitted
12 Aug 2004
Accepted
15 Oct 2004
First published
19 Nov 2004

Chem. Commun., 2005, 72-74

Synthesis and structural characterization of highly chlorinated C70, C70Cl28

S. I. Troyanov, N. B. Shustova, I. N. Ioffe, A. P. Turnbull and E. Kemnitz, Chem. Commun., 2005, 72 DOI: 10.1039/B412448K

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