Issue 18, 2004

Regio- and stereoselective hydrosilylation of terminal alkynes using Grubbs' first-generation olefin-metathesis catalyst

Abstract

Grubbs' first-generation, Ru metathesis complex 3 catalyses the hydrosilylation of terminal alkynes. The reaction exhibits an interesting selectivity profile that is dependent on the reaction concentration and more importantly on the silane employed.

Graphical abstract: Regio- and stereoselective hydrosilylation of terminal alkynes using Grubbs' first-generation olefin-metathesis catalyst

Article information

Article type
Communication
Submitted
30 Jun 2004
Accepted
30 Jul 2004
First published
13 Aug 2004

Org. Biomol. Chem., 2004,2, 2558-2562

Regio- and stereoselective hydrosilylation of terminal alkynes using Grubbs' first-generation olefin-metathesis catalyst

C. S. Aricó and L. R. Cox, Org. Biomol. Chem., 2004, 2, 2558 DOI: 10.1039/B409832C

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